Hexane n hexane 20 72 as published by safe work australia. Grace tang ssrl user lab manager office 650 9263467. The reactions of nbutyllithium or tbutyllithium are generally carried out in simple hydrocarbons such as pentane and hexane, ethers such as diethyl ether or thf and tertiary amines such as. Sigmaaldrich 401757 page 1 of 8 sigmaaldrich material safety data sheet version 4. Hexane microbial id chemicals msds hexane 1 section 1 chemical product and company identification msds name. Each notification may be associated with multiple companies. Sra class sop and to specific safety data sheets sds of chemicals in use see section. Material safety data sheet instant fame reagent 2 hexane microbial id chemicals msds hexane 2 chronic. The interdependent properties, such as pyrophoricity, solubility, stability, and aggregation, are tabulated and discussed. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, led manufacturing, and others. It is widely used as a polymerization initiator in the production of elastomers such as polybutadiene or styrenebutadienestyrene.
Material safety data sheet section 1 chemical product and company identification msds name. Butyllithium is widely use as a polymerization initiator in the production of elastomers such as polybutadiene or styrenebutadienestyrene sbs. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. Ghs h statement h225h250h260h252h304h361h373h314h336 highly flammable liquid and vapor. Nearly continuous exposure of animals at 250 ppm has caused neurotoxic effects. The starting material is fairly soluble in the solvent, but not at all in hexane, which is how the nbuli usually comes, i was wondering if. Overexposure to hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. The interdependent properties, such as pyrophoricity, solubility.
First aid measures eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Clear to slightly hazy colorless to yellow liquid molarity. Organolithium formation is carried out in hydrocarbon solvents. The term hexanes cas 110543 refers to a hydrocarbon distillation fraction that contains a mixture of linear and branched hexane isomers. Butyllithium 15% solution in n hexane for synthesis find msds or sds, a coa, data sheets and more information. No smoking p233 keep container tightly closed p240 groundbond container and receiving equipment. Risa benwell spl program manager office 650 9266283. Material safety data sheet northwest missouri state. Product and company identification product name n butyllithium, 2. Extreme high moderate low section 1 chemical product and company identification product name. It is also broadly employed as a strong base superbase in organic synthesis, both industrially and in the laboratory. Sensitivity to static discharge yes sensitivity to static impact not applicable 5. In contact with water releases flammable gases which may ignite spontaneously.
Procedures for safe use of pyrophoric solids, 22009 page 1 of 4 procedures for safe use of pyrophoric solids researchers should not use pyrophoric reagents until they have read and fully understood these safe operating procedures. Click to download the latest version of adobe reader. These properties have a direct bearing on their chemical reactivity and requirements for safe handling and storage. However, reading these procedures does not substitute for handson training. Hydrocarbons, c6, nalkanes, isoalkanes, cyclics, nhexane rich. Hexane is expected to rapidly volatilize leaving a deposit of n butyllithium behind. Twa the timeweighted average airborne concentration over an eighthour working day, for a fiveday working week over an entire working life. Show this safety data sheet to the doctor in attendance. Reproductive effects experiments have shown reproductive toxicity effects on laboratory animals. Material safety data sheet hexane 7 section 16 other information msds creation date. Similarly, flush doubletipped needles with hexane and then quench.
Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Identification of the substancemixture and of the companyundertaking 1. Preparation, properties, and safe handling of commercial. Safety data sheet northwest missouri state university. March 23, 2015 page 1 of 20 quenching of pyrophoric materials quenching of pyrophoric materials h250 h251 h252 examples. Prolonged or repeated skin contact may cause defatting and dermatitis. Health 3 4 fire 3 3 2 reactivity 2 personal protection. Insoluble in water, it is soluble in ether, alcohol, and acetone. None information in this msds is from available published sources and is believed to be accurate.
P202 do not handle until all safety precautions have been read and. Your new online msds binder is a place for you to store. No warranty, express or implied, is made and labchem inc. Skin contact wash off immediately with plenty of water for at least 15 minutes. Afterwards, lithium chloride is removed and the solution is concentrated to as much as 90% ww. Also, it is broadly employed as a strong base in the synthesis of organic compounds as in the pharmaceutical industry. Hexane 110543 not listed not listed not listed not listed not listed mutagenic effects mutagenic effects have occurred in experimental animals. Heating may cause a fire in contact with water releases flammable gases which may ignite spontaneously may cause fire or explosion. Lithium hydroxide, the oxidationhydrolysis product, is considered moderately toxic. Safety data sheet creation date 26oct2009 revision date 05jul2019 revision number 4 1. The term may refer to any of the five structural isomers with that formula, or to a mixture of them. Hexane 7 section 16 other information msds creation date. Safety data sheet according to 29cfr19101200 and ghs rev. Other companies are charging thousands of dollars to set up accounts and give you access to their.
Hazard statements h225 highly flammable liquid and vapour. Occupational polyneuropathy has resulted from hexane exposures as low as 500 ppm, but the minimum levels of n hexane that are neurotoxic in humans havent been established. To use this application, you will need the latest version of adobe reader. The information presented herein is believed to be accurate and reliable, but is.
Butyllithium 15% solution in nhexane for synthesis find msds or sds, a coa, data sheets and more information. Procedures for safe use of pyrophoric solids, 22009 page 3 of 4 specific recommendations for working with pyrophoric solid reagents lithium aluminum hydride reacts violently with water and has a. Draw hexane into the syringe containing small amounts of pyrophoric reagent and then discharge the diluted solution into isopropanol. In contact with water releases flammable gases which may ignite spontaneously danger substances and mixtures which in contact with water, emit.
Hexane is expected to rapidly volatilize leaving a deposit of nbutyllithium behind. H261 in contact with water releases flammable gases. Extreme high moderate low section 1 chemical product and company identification. This reagent is generally a mixture of several isomers of hexane c6h14. Hexanes typically contain a high proportion of nhexane. In iupac nomenclature, however, hexane is the unbranched isomer nhexane. In case of contact, immediately flush eyes with flowing water for at least 15 minutes. Your new online msds binder is a place for you to store the material safety data sheets you need to.
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